New Characters
Gogo
Honey Lemon
Wasabi
Fred
Gogo/Quorra
Gogo/Shank
Honey Lemon/Hiro
Honey Lemon/Joy
Wasabi/Hiro
Wasabi/Gizmoduck
Fred/Mushu
Fred/Baymax
For Quasimoto
Quasi/hercules
Quasi/Mickey
Quasimodo/The Beast
Quasimodo/Rapunzel
Gogo/Hiro
Honey Lemon/Hiro
Fred/Hiro
Wasabi/Baymax
How original 
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Quasimodo/Hercules
Quasimodo/Goliath
Gogo/Hiro
Gogo/Quorra
Honey Lemon/Joy
Honey Lemon/Olaf
Wasabi/Li Shang
Wasabi/Mr. Incredible
Fred/Rex
Fred/Genie
Gogo/Shank
Gogo/MP
HL/Wall-E
HL/Eeyore
Wasabi/Yax
Wasabi/Hiro
Fred/Mr. I
Fred/Mushu
Quasimodo/Stitch
Quasimodo/Mike
New characters:
Bushroot
Quackerjack
Liquidator
Negaduck
Bushroot/Dr. Facilier
Bushroot/Maleficent
QuackerJack/Yzma
QuackerJack/Negaduck
Liquidator/Megavolt
Liquidator/Ursula
Negaduck/Megavolt
Negaduck/Anger
Bushroot/Yax
Bushroot/Megavolt
Quackerjack/Oogie Boogie
Quackerjack/Zurg
Liquidator/Ursula (it just fits…)
Liquidator/The Queen of Hearts
Negaduck/Scar
Negaduck/Syndrome
Bushroot/Yzma
Bushroot/QoH
Quackerjack/Megavolt
Quackerjack/Zurg
Liquidator/Ursula
Liquidator/Honey lemon (to me it just makes sense)
Negaduck/Shan yu
Negaduck/Zurg
Bushroot/Joy
Bushroot/Yzma
Quackerjack/Queen of Hearts
Quackerjack/Megavolt
Liquidator/Finnick
Liquidator/Dr. Facilier
Negaduck/Jafar
Negaduck/Syndrome
New Villains from Buzz Lightyear of Star Command
NOS-4-A2
Torque
Warp Darkmatter
Gravitina
XL
OK, after everyone that I read, that’s my results for many of the previous:
Pete/Megavolt
Pete/King Louie
The Big Bad Wolf/Oogie Boogie
The Big Bad Wolf/Randall Boggs
Stromboli/Dr. Facilier
Stromboli/Madam Mim
Sebastian/Powerline
Sebastian/Gerald, Marlin & Nemo
Scuttle/WALL-E
Scuttle/Hank & Dory
Ludwig Von Drake/Scrooge McDuck
Ludwig Von Drake/Mickey Mouse
Tiana/Linguini & Remy
Tiana/The Mad Hatter
Prince Naveen/Miguel
Prince Naveen/Flynn Rider
Arthur/Vanellope
Arthur/Merlin
Wendy/Peter Pan
Wendy/Alice
Clayton/Gaston
Clayton/Shan Yu
Lilo/Stitch
Lilo/Powerline
Kermit/Gonzo
Kermit/Animal
Snow White/Minnie Mouse
Snow White/Belle
Esmeralda/Miguel
Esmeralda/Megara
Frollo/Shan Yu
Frollo/Scar
Rurke/Captain Hook
Rurke/Davy Jones
Gantu/Zurg
Gantu/Oogie Boogie
The Muses/Megara
The Muses/Powerline
Cruella De Vil/Ursula
Cruella De Vil/Maleficent
Tweedle dee and tweedle dum/Alice
Tweedle dee and tweedle dum/Belle
King Fergus/Merida
King Fergus/Chief Bogo
Kim Possible/Darkwing Duck
Kim Possible/Hiro Hamada
Go go/Dash
Go Go/EVE
Honey Lemon/Hiro
Honey Lemon/Yzma
Wasabi/Baymax
Wasabi/Hercules
Fred/Mike Wazowski
Fred/Mr. Incredible
Quasimodo/Ralph
Quasimodo/Sally
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NOS-4-A2/Baymax
Torque/Finnick
Warp Darkmatter/Zurg
Gravtina/Gaston
XL/WALL-E
New Characters:
Pocahontas
Blackbeard
Salazar
Mira (Mira: Royal Detective)